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O Levels - Periodic Table Guide

The periodic table is a cornerstone of chemistry, providing a comprehensive map of the elements and their properties. For O Level Pure Chemistry students, mastering the periodic table is essential. There are three subtopics that will be tested in exams – periodic trends, group properties, and transition elements. 

Here’s a detailed guide to help you understand and effectively use the periodic table.

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Periodic Trends

Arrangements of Elements in the Periodic Table 

The Periodic Table is an arrangement of elements in the order of increasing proton (atomic) number.

A horizontal row is called a period.

  • In each period, all elements have the same number of electron shells.
  • Across a period
    • Elements change from metals to non-metals.
    • Number of outer shell (valence) electrons increases.


A vertical column is called a
group.

  • In each group
    • All elements have the same number of outer shell (valence) electrons.  
    • All elements form ions of the same charge and compounds of similar formulae, thus they have the same chemical properties.
    • Down a group, number of electron shells increases.
Annotated periodic table highlighting groups and periods with explanations about shared properties and electron shells among elements in the same group or period.

Classes of Elements  

There are three main classes of elements: 

  1. Metals – left side of periodic table 
  2. Metalloids – along diagonal zigzag line
  3. Non-metals – right side of periodic table
Periodic table highlighting metals in yellow, metalloids in orange, and nonmetals in blue, with elements labeled by symbol and atomic number.

Group Properties

There are three groups of elements that we are particularly interested in.

  • Alkali metals (Group 1)
  • Halogens (Group 17) 
  • Noble gases (Group 18)


Alkali Metals (Group 1)

Group 1 elements, also known as alkali metals, are characterised by having only 1 valence electron in the valence shell. This singular electron defines many of their physical and chemical properties. 

Physical Properties of Alkali Metals 

  • Shiny and slivery 
  • Soft and easily cut 
  • Low density (Li, Na, K float on water)
  • Low melting and boiling point 
  • Good conductors of electricity and heat


Chemical Properties of Alkali Metals 

  • Tend to lose their valence electron to form positive ions with +1 charge (e.g., Li+
  • Highly reactive and have to be stored under oil or in vacuum to prevent them from reacting with moisture or air


Types of reactions: 

Reaction

Products 

React with non-metals 

Form ionic compounds

React with water

Form metal hydroxide and hydrogen gas

React with acid

Form salt and hydrogen gas

React with chlorine or air (O2

Form metal chloride or metal oxide

Trends of Alkali Metals 

 

Trend

Explanations

Melting / Boiling Point

Decreases

↑ number of electron shell, ↑ atomic radius, ↓ attractive forces between delocalised electrons and nucleus, ↓ energy needed to overcome metallic bond 

Density 

Increases

 

Reactivity

Increases

↑ number of electron shell, ↑ atomic radius, ↓ attractive forces between valence electron and nucleus, easier to lose electron to form cation 


Halogens (Group 17)

Halogens, found in Group 17 of the periodic table, are a fascinating group of non-metals known for their high reactivity and distinctive properties. With 7 valence electrons in the valence shell, halogens are just one electron short of achieving a stable noble gas configuration. As such, they exists as diatomic molecule (e.g., F2) to achieve electronic stability. 

Physical Properties of Halogens 

  • Brittle in solid state
  • Coloured molecules (darker down the group)
  • Low melting and boiling points
  • Poor conductor of heat and electricity


Chemical Properties of Halogens  

  • Tend to gain electron to fill valence shell and form negative ions with -1 charge (e.g., F, Cl).
  • Very reactive 


Types of reactions:

Reaction

Products 

React with metals 

Form ionic compounds (metal halide)

React with another non-metals 

Form covalent compounds

Trends of Halogens

 

Trend

Explanations

Melting / Boiling Point

Increases

↑ number of electron shell, ↑ number of electrons, ↑ strength of intermolecular forces of attraction between molecules, ↑ energy needed to overcome attractive force

Density 

Increases

 

Reactivity

Decreases

↑ number of electron shell, ↑ atomic radius, ↓ attractive forces between valence electron and nucleus, harder to gain electron to form anion

Halogen Displacement 

Halogen displacement reactions are a key concept in understanding the reactivity trends within Group 17 elements. These reaction occur when a more reactive halogen can displace the less reactive halide ion from its compound or solution.

Reactivity Order

The reactivity of halogens decreases down Group 17, with fluorine being the most reactive, followed by chlorine, bromine, and iodine (F > Cl > Br > I). For example, when chlorine gas (Cl2) is added to a solution containing bromide ions (Br), the chlorine will displace the bromine, forming chloride ions (Cl) and free bromine (Br2):

Cl2​ + 2Br→ 2Cl+ Br2

Observation of Displacement: 

The identity of halogens during halogen displacement can be easily inferred from its colour and physical state as shown below. 

 

F

Cl

Br2 

I2

Colour

Pale yellow 

Pale-greenish yellow

Reddish-brown

Black

Physical state at r.t.p

Gas 

Gas 

Liquid 

Solid


Noble Gases (Group 18)

Noble gases, found in Group 18 of a periodic table, are unique due to their fully filled valence electron shells. This configuration allows them to exist as monatomic atoms (e.g., Ar, Ne) and makes them extremely stable and largely unreactive. Here’s a closer look at their properties and uses:

Physical Properties of Noble Gases

  • Colourless gases at r.t.p
  • Low melting and boiling points 


Chemistry Properties of Noble Gases

  • Inert and extremely unreactive (due to their electronic stability)


Uses of Noble Gases 
Noble gases are widely used due to their lack of reactivity. For example, 

  • Helium is used to fill balloons and airships, as it is non-flammable, low density, and safe to use. 
  • Neon is used in advertising signs and fluorescent lights, as it glows when electrically excited. 
  • Argon makes up about 1% of Earth’s atmosphere and is used in bulbs to prevent filament from oxidising and burning out quickly. 

Transition Elements

Transition elements, located in the central block of the Periodic Table (between Group 2 and 13), are metals that exhibit unique properties compared to the main group elements. These elements include iron, copper, nickel, and many others. 

Physical Properties of Transition Elements 

  • Higher melting and boiling points (compared to group 1 metals, except mercury)
  • Higher densities (compared to group 1 metals)
  • Hard, tough and strong
  • Good conductors of heat and electricity
  • Malleable and ductile


Chemical Properties of Transition Elements 

  • Has variable oxidation states (e.g., iron can exist as iron (II), Fe2+, or iron (III), Fe3+)
  • Formed coloured compounds and ions in solution (except zinc which is colourless)
  • Good catalysts (due to their ability to be oxidised and reduced easily)

Final Comments

Understanding the periodic table is essential for mastering O-Level Chemistry. These concepts not only provide the foundation for other chemistry topics, but also help in making sense of the chemical reactions and properties observed in everyday life. Keep exploring, questioning, and connecting the dots—this is the essence of learning chemistry.

Find this helpful? Find out more by joining us at Science of Studying! 

Prepared by: Tan Wee Leng

 

This article is written based on the 6092 Chemistry GCE Ordinary Level Syllabus. https://www.seab.gov.sg/docs/default-source/national-examinations/syllabus/olevel/2024syllabus/6092_y24_sy.pdf

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